马海燕 教授博士🚴🏿♀️，博士生导师
研究方向：金属有机化学，均相催化聚合
办公地址☁️：实验三楼415室
办公电话🦹♂️🙅🏿♂️：＋86 21 64253519
Email：haiyanma@ecust.edu.cn
研究生招生专业🚌：
博士研究生：1、有机化学；2🧘🏽🏄🏿♀️、工业催化
硕士研究生🧍♂️：1、有机化学、2、应用化学
专业学位研究生✡️😌：1🏊🏻♂️、材料与化工
1991年至2001年于杏悦娱乐化学系学习🤾🏻♀️，先后获工学学士⏱、理学硕士和工学博士学位。2001年5月赴德国留学深造，在乌尔姆大学Bernhard Rieger教授课题组进行博士后研究。2002年6月至2003年9月获德国洪堡基金会资助在德国美茵兹大学化学系Jun Okuda教授课题组做客座研究，并于2003年10月随Okuda教授迁至亚琛工业大学化学系🧜🏽♂️，从事博士后研究工作🦸🏿。2005年6月聘为杏悦教授。主要研究方向为新型金属有机络合物的分子设计、合成以及其可控催化非极性单体如烯烃🤸🏼♀️、二烯烃等𓀓，极性单体如丙交酯、环内酯等聚合、共聚反应的研究。目前已在国内外知名学术期刊及会议上发表学术论文130余篇🧙🏼，其中SCI论文70余篇，被SCI收录引用2240次，他引近2137次🎚，其中单篇论文最高引用率达254余次，H因子23👩🔧。获授权中国专利39项🧑🏻🦱。所参与的科研项目“新型高效、高选择性茂钛族金属催化剂的分子设计、合成及催化行为研究”获2004年上海市科技进步二等奖（第四完成人）👩🏼🎨🧑🏽🚒。2006年获上海市科技启明星计划、教育部新世纪优秀人才支持计划🧪。目前作为项目负责人已完成、承担国家自然科学基金项目6项，教育部重点项目1项🧛🏿，新世纪人才计划项目👬，上海市启明星计划项目以及中央高校基本科研项目🤷♂️，以及企业合作项目多项🧒🏻。
目前承担项目情况：
1）国家自然科学基金面上项目（2019.01~2022.12）：金属手性锌、镁配合物催化外消旋丙交酯等规选择性聚合研究
2）与山东京博企业合作项目（2020.06~2023.02）：定制结构金属有机催化剂合成工艺开发
3）与万华化学企业合作项目（2022.02~2025.06）：聚烯烃用催化剂的合成技术开发
主要研究领域：
1）设计合成基于生物相容性金属的各类结构明确金属络合物✦👩💻，用于催化内酯⏏️、交酯、环碳酸酯等开环聚合🧙🏼，以及环氧化物与酸酐⭐️、CO2等开环交替共聚等。通过分子水平的催化剂结构设计，来实现对聚合物立体规整性、链序列结构的有效控制⛱，获得新型结构可控🗝🤜、生物可降解型绿色聚酯、聚碳酸酯材料💁🏼♀️。
2）设计合成基于钛族金属🥼、后过渡金属以及稀土金属的各类结构明确金属络合物，用于催化烯烃🧑🏿🏫、二烯烃、环烯烃等聚合以及齐聚反应👩🏿🦳。通过分子水平的催化剂结构设计来实现对烯烃聚合过程、烯烃聚合产物结构的可控可调🟰，包括聚合物链立体规整性、分子量及分布🧝🏿♀️、共聚单体分布📆、支化度等的可控可调，以获得结构可控、性能优异的新型聚烯烃材料。
英文专著✳️、译著章节：
l Haiyan Ma, Jiling Huang,“Chapter 14 Tactic Polystyrene and Styrene Copolymers”, Stereoselective Polymerization with Single-Site Catalysts, 2008, 363-397. Edited by Lisa Saunders Baugh/ Canich, Jo Ann M./ Coughlin, E. Bryan. Published by CRC Press, Taylor & Francis Group. ISBN-13：978-1-57444-579-4.
l 马海燕译。《过渡金属有机化学》，杏悦娱乐出版社🧑🏿🦲，2017年9月。ISBN🦠：978-7-5628-5111-0。（原著[美] Robert H. Crabtree）
代表性论文：
1. 张雷，马海燕𓀝，“亚乙基桥联多取代茚-芴锆、铪配合物的合成🛐🧑🏻🎓、结构及催化丙烯选择性齐聚研究”, 化学学报（Acta Chim. Sinica）, 2020, 78, 778—787.
2. Yanmei Gong and Haiyan Ma*, “High performance benzoimidazolyl-based aminophenolate zinc complexes for isoselective polymerization of rac-lactide”, Chem. Commun., 2019, 55, 10112–10115.
3. Lei Zhang, bin Zhang, Haiyan Ma*, “Ethylene-bridged indenyl-fluorenyl metallocene complexes for efficient preparation of allyl-terminated propylene oligomers and polymers via selective β-methyl transfer”, Chin. J. Polym. Sci., 2019, 37(6), 578–590.
4. Jianwen Hu, Chao Kan, Haobing Wang,* and Haiyan Ma*, “Highly active chiral oxazolinyl aminophenolate magnesium initiators for isoselective ring-opening polymerization of rac-lactide: dinuclearity induced enantiomorphic site control”, Macromolecules, 2018, 51, 5304−5312.
5. Jianwen Hu, Chao Kan, and Haiyan Ma*, “Exploring steric effects of zinc complexes bearing achiral benzoxazolyl aminophenolate ligands in isoselective polymerization of rac-lactide”, Inorg. Chem,. 2018, 57, 11240−11251.
6. Chao Kan, Jianwen Hu, Yang Huang, Haobing Wang,* and Haiyan Ma*, “Highly isoselective and active zinc catalysts for rac-lactide polymerization: effect of pendant groups of aminophenolate ligands”, Macromolecules, 2017, 50, 7911-7919.
7. Yang Yang, Haobing Wang, Haiyan Ma*, “Unprecedented reaction pathway of sterically crowded calcium complexes: sequential C−N bond cleavage reactions induced by C−H bond activations”, Chem. An Asian J., 2017, 12(2), 239-247.
8. Haobing Wang, Yang Yang, Haiyan Ma*, “Exploring steric effects in diastereoselective synthesis of chiral aminophenolate zinc complexes and stereoselective ring-opening polymerization of rac-lactide”, Inorg. Chem. 2016, 55, 7356−7372.
9. Chao Kan, Haiyan Ma*, “Copolymerization of L-lactide and 3-caprolactone catalyzed by mono-and dinuclear salen aluminum complexes bearing bulky 6,6’-dimethylbipheyl-bridge: random and tapered copolymer”, RSC Adv., 2016, 6, 47402–47409.
10. Yang Yang, Haobing Wang, Haiyan Ma*, “Stereoselective polymerization of rac-lactide catalyzed by zinc complexes with tetradentate aminophenolate ligands in different coordination patterns: kinetics and mechanism”, Inorg. Chem., 2015, 54 (12), 5839-5854.
11. Haobing Wang, Yang Yang, Haiyan Ma*, “Stereoselectivity switch between zinc and magnesium initiators in the polymerization of rac-lactide: different coordination chemistry, different stereocontrol mechanisms”, Macromolecules, 2014, 47, 7750-7764.
12. Ruiguo Zhao, Taotao Liu, Liying Wang, Haiyan Ma*, “High temperature ethylene polymerization catalyzed by titanium (IV) complexes with tetradentate aminophenolate ligands in cis-O, N, N chelating mode”, Dalton Trans., 2014, 43(33), 12663-12677.
13. Aike Li, Haiyan Ma,* and Jiling Huang*, “Highly thermally stable eight-coordinate dichloride zirconium complexes supported by tridentate [ONN] ligands: syntheses, characterization, and ethylene polymerization behavior”, Organometallics, 2013, 32, 7460-7469.
14. Wei Yi, Haiyan Ma*, “Magnesium and calcium complexes containing biphenyl-based tridentate iminophenolate ligands for ring-opening polymerization of rac-lactide”, Inorg. Chem., 2013, 52, 11821-11835.
15. Haobing Wang, Haiyan Ma*, “Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide”, Chem. Commun., 2013, 49 (77), 8686 – 8688.
16. Yuan Wang, Haiyan Ma,* “Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and L-lactide”, Chem. Commun., 2012, 48, 6729-6731.
17. Liying Wang, Haiyan Ma*, “Highly active magnesium initiators for ring-opening polymerization of rac-lactide”, Macromolecules, 2010, 43, 6535-6537.
18. Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Rare-earth metal complexes supported by 1,ω-dithiaalkanediyl-bridged bis(phenolato) ligands: synthesis, structure, and heteroselective ring-opening polymerization of rac-lactide”, Inorg. Chem. 2008, 47, 3328-3339.
19. Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Highly heteroselective ring-opening polymerization of rac-lactide initiated by bis(phenolato) scandium complexes”, Angew. Chem. Int. Ed. Engl. 2006, 45, 7818-7821. VIP article.
20. Haiyan Ma, Jun Okuda, “Kinetics and mechanism of L-lactide polymerization by rare earth metal silylamido complexes: the effect of alcohol addition”, Macromolecules, 2005, 38, 2665-2673.